First of all: Why should we feel offended by your request

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1) Try SPU Eternal instead of PEOpS SPU (better quality for example). Choose a small buffer size (but not too small, because it might crackle), enable SPUAsync -> Wait (and disable Frame Limitation in your gfx plugin). This will syncronize XA sound and MDECs.
2) Does this only happen at the logo? If yes, play the game and wait for the next release of ePSXe...
Post Scriptum: When setting up the buffer size, play around with the realtime config window.
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