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Basically, I make an image of a PSX game, and then copy the image file to a CD. This is handy because some games use much less than the whole CD; I can often fit 2 games to a disc... and if you ever need to make a backup of the backups, you get the benefit of being able to copy two or three games at once...
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I think I found your BIGGEST mistake here. It seems that you merge 2 games into 1 CD, right? Well, thats the problem. Even for one PSX game, you can NOT just copy and paste like using Nero. But you need to use burning software that capable to make 1:1 ISO like CloneCD.