Butz, Lenna, Faris, Galuf and the Tycoon Kingdom
I think it had Exdeath as the main boss, even though those usually aren't too memorable in any FF which involves chasing crystals. FFV has the exact same spot for me as it has for you Densetsu: It was my first emulated SNES game. I have the original boxed version at home, rather cool I'd say.
@ Squall: True, while entertaining it probably doesn't reach those levels. The thing with these open job systems is that you have less options to personalize the characters.