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1.2 Ghz Celeron will definately perform better than P3 800, other than the 400 Mhz increase, your gfx card will probably bottlneck on a Geforce 2 MX, but the Geforce 3 TI wouldn't. won't matter too much for emulation.
I got a huge performance increase when I put a new 1.3 Ghz Duron in place of my 900 Mhz Duron, And changed my geforce 2 MX to a Geforce 4 MX
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