Yes, It's just that it appears on the previous page since this lot have been so busy yakking about ClearType, donutbandit!
You & me would never go off topic like that, would we?
I presume you haven't changed the relevant settings in the Frontend, then - don't forget there are no global settings there, each profile has to be changed individually. You can open psxfrontend.ini in a text editor and change the lot with Find/Replace All if you're careful. Make a backup first, though! I can't remember if there's a setting for VSync in the Windows version, but I think there is.