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As you could easily have learned from searching the forums via the search button at the top (Titles only - "quad"). There are no plans to support it.
As for the second question (Which has nothing to do with PCSX2), quad cores are cheap enough that you might well want to consider getting one. However, for almost all current software (With the exception of video encoding and other specialized tasks) you'd notice no real increase in performance, unless you multi-task *very* heavily (Like compressing a rar, running PCSX2 in dual core mode, and watching porn encoded using the H.264 codec on your second monitor all at the same time).
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