As nice distros, I would recommend keeping a copy of SAM Linux 2007, and Puppy Linux 2.16 available on CD's at all times, to prevent disasters, and unproductive periods. Those work directly from CD's, and dont require hard drives for operation (provided there is enough ram obviously).
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SAM Linux 2007 is a buffed up clone of PCLinuxOS 2007
(with added codecs, convenient softs, usability and 3d effects that makes it a visually attractive, appropriate, quality choice especially for first-timers).
Note:PCLinuxOS is itself Mandriva-based.
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Puppy Linux is a superlightweight distro that fits into 128 megas of ram and works fast/reliably on very old computers. Keep those P II's handy, cuz there's still hope for 'em.
Can also boot from a USB drive as well.
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That should be enough for now. Let's keep room for creative additions.
I'll add a few softs here later. Distributions first.
Also, a few links, or repository links wouldnt be too bad. Let me remember the biggest repository's adress and I'll be right back. Yes, even bigger than Debian's.