You cant set the controls (unless you change it in the source and compile it yourself).
Also as for the default controls, you should always read a programs read-me before asking questions, this is taken from it.
Quote:
Keyboard controls:
1 - START
Y - Y
X - X
Z - Z
[ - Button L
] - Button R
I,J,K,L - Digital keypad
Up, Left, Down, Right - Analog stick
E,S,D,F - C analog stick
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